Compounds | Reactions | Production
|
Reactions of Plutonium |
Reactions with air |
Plutonium reacts readily with oxygen, forming PuO and PuO2, as well as intermediate oxides. |
Reactions with halogens |
It reacts with the halogens, giving rise to compounds such as PuX3 where X can be F, Cl, Br or I; PuF4 and PuF6 are also seen. |
Other reactions |
It will react with carbon to form PuC, nitrogen to form PuN and silicon to form PuSi2. |
Reduction Potentials | |
Balanced half-reaction | E0 / V |
Pu4+ + e-Pu3+ | +0.970 |
Pu3+ + 3e-Pu(s) | -2.03 |
PuO22+ + 4H+ + 2e-Pu4+ + 2H2O | +1.04 |
PuO22+ + e-PuO2+ | +0.916 |
Pu(OH)3(s) + 3e-Pu(s) + 3OH- | -2.42 |
Pu(OH)4(s) + e-Pu(OH)3(s) + OH- | -0.95 |